By Joshua Jortner, Raphael D. Levine, Stuart Alan Rice
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Additional resources for Advances in Chemical Physics (Wiley Series in Probability and Mathematical Statistics)
The vibrational temperature was determined by linear interpolation to calculate the temperature and partition function, which yield the given average energy per molecule. ’” The summation was carried out for all fundamental levels, their overtones up to about 2500 cm-I, and all combinations thereof, using accepted values of SF, harmonic energy levels and degeneracies. This direct count yields a vibrational partition function within 1% of that computed by the method of infinite series of energy-level overtones.
INFRARED LASER-ENHANCED DIFFUSION CLOUD REACTIONS 45 VACUUM PUMP 1 c II I TRANSIENT RECORDER VARIABLE ATTENUATOR c-’, I TR -:‘,,:: YB RESONANCE LAMP C02 LASER ROTATING MIRROR ARGON REACTANT TEMPERATURE Fig. 1. Schematic diagram of the laser-excited diffusion cloud apparatus. Steady-state reactions can be observed in this apparatus by causing the sodium cloud to fluoresce with light from a sodium resonance lamp. When the oven is heated, and the carrier gas is flowed through the oven, the sodium cloud is seen to fill the cell.
B) J. Brzozowski, P. Erman, and M. Lyyra, Phys. Scripta, 14, 290 (1976). B. L. Earl and R. R. Herm, J. Chem. , 60,4568 (1974). R. Bersohn and H. Horowitz, J. Chem. , 63, 48 (1975). F. Ackerman and E. Miescher, J. Mol. Spectry, 31, 400 (1969). 0. Benoist d'Azy, R. Lopez Delgado, and A. Tramer, Chem. , 9, 327 (1975). A. B. Callear, M. J. Pilling, and I. W. M. Smith, Trans. ,64, 2296 (1968). J. 0. Hirschfelder, C. E. Curtiss, and R. B. Bird, Molecular Theory of Guses and Liquids, Wiley, New York, 1964.
Advances in Chemical Physics (Wiley Series in Probability and Mathematical Statistics) by Joshua Jortner, Raphael D. Levine, Stuart Alan Rice